oilman
27-07-2010, 16:49
What are the differences, in layman's terms, between mineral, semi-synthetic and fully-synthetic engine oil?
Before we get into details, the first thing to realise that there is no chalk and cheese difference between mineral and synthetic based oils. After all, the chemical compounds which make mineral engine oils so much better are themselves synthetic. Synthetic lubricant bases are stepwise improvements on mineral oil, with more desirable properties and fewer undesirable ones.
The second important point is that there's no one thing called 'synthetic'! There are several different types of synthetic lubricant, and to say something like: 'the Supergrunt XXR must have a full synthetic' is meaningless unless the 'expert' explains what sort of synthetic he means.
Equally, to imply that dreadful things will happen if the 1970 Hardley-Ableson Bluegrass is run on anything other than Pennsylvania mineral is ridiculous. It may not need a 2007 synthetic, but it isn't going to come to any harm if the owner uses a 2007 synthetic.
The most basic type of synthetic is really a special mineral oil. Known as 'hydrocracked' bases, these are made in oil refineries by putting certain types of mineral fraction through special processing, so they cost more than the usual mineral types but not much more. They are useful because they resist evaporation at high temperatures. Although used for years for genuine technical reasons, they are now popular with marketing men because the magic sexy word 'synthetic' can legitimately be printed on the label without spending much on the oil inside the can!
Yes, all low-cost 'synthetics' contain anything from a few percent to 20 percent (i.e. 'semi-synthetic') of special mineral oil.
Using fairly simple chemical compounds or gases from oil refineries or other sources, it is possible to 'synthesise' or build up tailor-made lubricant molecules which have very desirable characteristics, such as great resistance to cold, heat, evaporation losses or excessive thinning as they get hot.
These are the true synthetics, and the two that are used in engine oils are PAOs (poly alpha olefins) and esters. Neither is cheap! PAOs are related to mineral oils, and are the ideal carriers for all the chemical compounds used in mineral oils. Because they do not gel at very low temperatures, all genuine 0W-something oils have to be based on PAOs to pass the 0W test at a sub-arctic -35C.
Esters were originally made for jet engine lubricants, and to this day all jet oils are ester-based. Although similar in performance to PAOs, they have a valuable extra trick: they are good lubricants and help to protect metal surfaces.
As 0W- and 5W- grades are not usually recommended for motorcycles,perhaps the best all-round oil is a 10W/40 shear-stable semi-synthetic with some ester content. Esters help with transmission and valve train lubrication. 100% fully-synthetic oils are actually quite rare, probably because they are very expensive to make, and even more expensive to buy.
Even so, an ester/PAO with a very shear stable multigrade polymer is the ultimate oil for high output engines that are worked hard, which means racing.
Before we get into details, the first thing to realise that there is no chalk and cheese difference between mineral and synthetic based oils. After all, the chemical compounds which make mineral engine oils so much better are themselves synthetic. Synthetic lubricant bases are stepwise improvements on mineral oil, with more desirable properties and fewer undesirable ones.
The second important point is that there's no one thing called 'synthetic'! There are several different types of synthetic lubricant, and to say something like: 'the Supergrunt XXR must have a full synthetic' is meaningless unless the 'expert' explains what sort of synthetic he means.
Equally, to imply that dreadful things will happen if the 1970 Hardley-Ableson Bluegrass is run on anything other than Pennsylvania mineral is ridiculous. It may not need a 2007 synthetic, but it isn't going to come to any harm if the owner uses a 2007 synthetic.
The most basic type of synthetic is really a special mineral oil. Known as 'hydrocracked' bases, these are made in oil refineries by putting certain types of mineral fraction through special processing, so they cost more than the usual mineral types but not much more. They are useful because they resist evaporation at high temperatures. Although used for years for genuine technical reasons, they are now popular with marketing men because the magic sexy word 'synthetic' can legitimately be printed on the label without spending much on the oil inside the can!
Yes, all low-cost 'synthetics' contain anything from a few percent to 20 percent (i.e. 'semi-synthetic') of special mineral oil.
Using fairly simple chemical compounds or gases from oil refineries or other sources, it is possible to 'synthesise' or build up tailor-made lubricant molecules which have very desirable characteristics, such as great resistance to cold, heat, evaporation losses or excessive thinning as they get hot.
These are the true synthetics, and the two that are used in engine oils are PAOs (poly alpha olefins) and esters. Neither is cheap! PAOs are related to mineral oils, and are the ideal carriers for all the chemical compounds used in mineral oils. Because they do not gel at very low temperatures, all genuine 0W-something oils have to be based on PAOs to pass the 0W test at a sub-arctic -35C.
Esters were originally made for jet engine lubricants, and to this day all jet oils are ester-based. Although similar in performance to PAOs, they have a valuable extra trick: they are good lubricants and help to protect metal surfaces.
As 0W- and 5W- grades are not usually recommended for motorcycles,perhaps the best all-round oil is a 10W/40 shear-stable semi-synthetic with some ester content. Esters help with transmission and valve train lubrication. 100% fully-synthetic oils are actually quite rare, probably because they are very expensive to make, and even more expensive to buy.
Even so, an ester/PAO with a very shear stable multigrade polymer is the ultimate oil for high output engines that are worked hard, which means racing.